纳米科学技术及其在军事领域的应用展望

本文对作21世纪高新技术之一的纳米科学技术进行了阐述，并结合当前国内外的进展，就其在军用新材料技术，隐身技术，武器研制技术和军用电子技术等四个领域中在未来军事战争中的应用进行了阐述和展望。     

Numerical simulation of the rheological properties of granular composites by using a structural approach

Composites with an elastomeric matrix containing rigid particles of diameter 10–1000 μm are studied. One of possible mechanisms of the rheological behavior of such filled systems, related to the origination and growth of vacuoles near the rigid inclusions in a viscous matrix, is considered. For simulating the mechanism of formation of rheological properties of the filled elastomers, we use a structural cell in the form of an elastomeric cylinder, whose height and diameter are equal in magnitude, with a rigid spherical inclusion at its center. Deformation of the cells is examined with the observance of boundary conditions providing the preservation of their close packing. The inclusion is assumed to be rigid, and the matrix properties are described by equations of the linear hereditary viscoelasticity theory. The formation of vacuoles is described by using the approach suggesting that an initial debonding begins to propagate when the energy accumulated in the extended matrix reaches a value sufficient to create a new interface. The heterogeneity of the composite is simulated by taking into account the variability of the local filler concentration. Creep curves obtained for composite cells with different content of the solid phase are presented. Comparisons between the numerical and experimental results show a satisfactory agreement. Translated from Mekhanika Kompozitnykh Materialov, Vol. 44, No. 6, pp. 895–906, November–December, 2008.     

Braided reinforced composite rods for the internal reinforcement of concrete

This paper reports on the development of braided reinforced composite rods as a substitute for the steel reinforcement in concrete. The research work aims at understanding the mechanical behaviour of core-reinforced braided fabrics and braided reinforced composite rods, namely concerning the influence of the braiding angle, the type of core reinforcement fibre, and preloading and postloading conditions. The core-reinforced braided fabrics were made from polyester fibres for producing braided structures, and E-glass, carbon, HT polyethylene, and sisal fibres were used for the core reinforcement. The braided reinforced composite rods were obtained by impregnating the core-reinforced braided fabric with a vinyl ester resin. The preloading of the core-reinforced braided fabrics and the postloading of the braided reinforced composite rods were performed in three and two stages, respectively. The results of tensile tests carried out on different samples of core-reinforced braided fabrics are presented and discussed. The tensile and bending properties of the braided reinforced composite rods have been evaluated, and the results obtained are presented, discussed, and compared with those of conventional materials, such as steel. Russian translation published in Mekhanika Kompozitnykh Materialov, Vol. 44, No. 4, pp. 327–338, May–June, 2008.     

Low‐temperature sol–gel transformation of methyl silicon precursors to silica‐based hybrid materials

Six new methyl silicon (IV) precursors of the type [MeSi{ON?C(R)Ar}₃] [when R = Me, Ar = 2‐C₅H₄N ( 1 ), 2‐C₄H₃O ( 2 ) or 2‐C₄H₃S ( 3 ); and when R = H, Ar = 2‐C₅H₄N ( 4 ), 2‐C₄H₃O ( 5 ) or 2‐C₄H₃S ( 6 )] were prepared and structurally characterized by various spectroscopic techniques. Molecular weight measurements and FAB (Fast Atomic Bombardment) mass spectral studies indicated their monomeric nature. ¹H and ¹³C{¹H} NMR spectral studies suggested the oximate ligands to be monodentate in solution, which was confirmed by ²⁹Si{¹H} NMR signals in the region expected for tetra‐coordinated methylsilicon (IV) derivatives. Thermogravimetric analysis of 1 revealed the complex to be thermally labile, decomposing to a hybrid material of definite composition. Two representative compounds ( 2 and 4 ) were studied as single source molecular precursor for low‐temperature transformation to silica‐based hybrid materials using sol–gel technique. Formation of homogenous methyl‐bonded silica materials (MeSiO_3/2) at low sintering temperature was observed. The thermogravimetric analysis of the methylsilica material indicated that silicon‐methyl bond is thermally stable up to a temperature of 400 °C. Reaction of 2 and Al(OPrⁱ)₃ in equimolar ratio in anhydrous toluene yielded a brown‐colored viscous liquid of the composition [MeSi{ON?C(CH₃)C₄H₃O}₃.Al(OPrⁱ)₃]. Spectroscopic techniques ¹H, ¹³C{¹H}, ²⁷Al{¹H} and ²⁹Si{¹H} NMR spectra of the viscous product indicated the presence of tetracoordination around both silicon and aluminum atoms. On hydrolysis it yielded methylated aluminosilicate material with high specific surface area (464 m²/g). Scanning electron micrography confirmed a regular porous structure with porosity in the nanometric range. Copyright © 2008 John Wiley & Sons, Ltd.     

Microstrain in hydroxyapatite carbon nanotube composites

Synchrotron radiation diffraction data were collected from hydroxyapatite–carbon nanotube bioceramic composites to determine the crystallite size and to measure changes in non‐uniform strain. Estimates of crystallite size and strain were determined by line‐profile fitting of discrete peaks and these were compared with a Rietveld whole‐pattern analysis. Overall the two analysis methods produced very similar numbers. In the commercial hydroxyapatite material, one reflection in particular, (0 2 3), has higher crystallite size and lower strain values in comparison with laboratory‐synthesized material. This could indicate preferential crystal growth in the [0 2 3] direction in the commercial material. From the measured strains in the pure material and the composite, there was a degree of bonding between the matrix and strengthening fibres. However, increasing the amount of carbon nanotubes in the composite has increased the strain in the material, which is undesirable for biomedical implant applications.     

Primes of the form <Emphasis Type="Italic">x</Emphasis><Superscript>2</Superscript> + (<Emphasis Type="Italic">x</Emphasis> + 1)<Superscript>2</Superscript>. Proper divisors of composites of the same form

The aim of the present paper is to characterize prime numbers of the form n = x ² + (x + 1)² and to obtain certain proper divisors of composite numbers of the same form, i.e. divisors d of n such that 1 < d < n.      

Entropy criterion of random states for granular material in a mixing process

Mathematical assessment of homogenisation progress of the granular material mixing process is presented. The mixing process was realised using a vessel in the form of two partly penetrating horizontal cylinders equipped with two multi-ribbon agitators. The experimental system consisted of three sets of particles of different colour. Random states of the mixed granular material were characterised by the sampling procedure at different moments of the mixing process. Informational entropy as well as the flow of quantum of information were applied to describe the progress of the homogenisation process. Analysis of this process was based on experimental investigations in the form of informational entropy patterns and described by means of the average informational entropy or the quantum of information. Presented at the 34th International Conference of the Slovak Society of Chemical Engineering, Tatranské Matliare, 21–25 May 2007.     

Hybrid materials of MCM-41 functionalized by lanthanide (Tb, Eu) complexes of modified meta-methylbenzoic acid: Covalently bonded assembly and photoluminescence

Novel organic-inorganic mesoporous hybrid materials were synthesized by linking lanthanide (Tb³⁺, Eu³⁺) complexes to the mesoporous MCM-41 through the modified meta-methylbenzoic acid (MMBA-Si) using co-condensation method in the presence of the cetyltrimethylammonium bromide (CTAB) surfactant as template. The luminescence properties of these resulting materials (denoted as Ln-MMBA-MCM-41, Ln=Tb, Eu) were characterized in detail, and the results reveal that luminescent mesoporous materials have high surface area, uniformity in the ordered mesoporous structure. Moreover, the mesoporous material covalently bonded Tb³⁺ complex (Tb-MMBA-MCM-41) exhibits the stronger characteristic emission of Tb³⁺ and longer lifetime than Eu-MMBA-MCM-41 due to the triplet state energy of organic legend MMBA-Si matches with the emissive energy level of Tb³⁺ very well.     

On two models in the three-dimensional theory of stability of composites

A comparative analysis is made of the infinite-fiber and finite-fiber models in the three-dimensional theory of stability of composites. The results analyzed have been obtained using the three-dimensional linearized theory of stability of deformable bodies. A historical sketch is given of the theory of stability for and approaches used in the mechanics of laminated and fibrous composite materials Translated from Prikladnaya Mekhanika, Vol. 44, No. 8, pp. 3–31, August 2008.